Title

Electrospray tandem mass spectrometry of oxo complexes of chromium, manganese and tuthenium

Document Type

Article

Publication Date

1994

Publication Title

Journal of the Chemical Society, Chemical Communications

Issue

12

First Page

1487

Last Page

1488

Abstract

Several oxometal species including MnO4 -, Cr 2O7 2-, CrO3Cl-, RuO 4 -, RuO2Cl3 - and [Ru(TMC)O2]2+ (TMC = 1,4,8,11-tetramethyl-1,4,8,11- tetraazacyclotetradecane) have been studied by electrospray tandem mass spectrometry; in each case the mass spectrum obtained from solution in acetonitrile shows the molecular ion as the base peak with a minimal degree of fragmentation.