Title

Alkynedicobalt Complexes in gamma-Carbonyl Cations and Cycloheptynedicobalt Complexes

Document Type

Article

Publication Date

2012

Publication Title

Synlett

Volume

23

Issue

9

Keywords

carbocation, alkyne complexes, transition-metal, Umpolung, ring closure

Abstract

This Account describes our work on highly electrophilic gamma-carbonyl cations featuring propargyldicobalt cations, cycloheptynedicobalt complexes, and the interconnection between the two systems.

Comments

The Accepted Version will be available for download after a 12 month embargo period. The definitive version is published in Synlett and is available here. Copyright (2012) Georg Thieme Verlag KG.