Document Type

Article

Publication Date

5-2017

Publication Title

Dalton Transactions

Volume

46

First Page

9769

Last Page

9776

DOI

10.1039/C7DT01345K

Abstract

The synthesis of novel trithiobisphosphines is achieved by oxidative addition of tetrathiocins to the phosphorus(I) reagent [PIdppe][Br] in good yields under ambient conditions. These trithiobisphosphines and the related intermediate diphosphine species are characterized by X-ray diffraction and multinuclear NMR and a mechanism is proposed for the formation of these molecules.

Comments

This is an accepted manuscript. The version of record is available at https://doi.org/10.1039/C7DT01345K.

Available for download on Tuesday, May 01, 2018

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