Date of Award
1993
Publication Type
Doctoral Thesis
Degree Name
Ph.D.
Department
Chemistry and Biochemistry
Keywords
Chemistry, Inorganic.
Supervisor
Stephan, D. W.,
Rights
info:eu-repo/semantics/openAccess
Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-No Derivative Works 4.0 International License.
Abstract
The reactions of Cp$\rm\sb2TiCl\sb2$ with the dithiols, HS(CH$\sb2)\sb{\rm n}$SH (n = 2, 3) in the presence of imidazole proceed with formation of imidazole$\cdot$HCl affording relatively insoluble titanocene dithiolate derivatives 2.1 and 2.2 respectively. Alternatively, 2.2 can be prepared by the reaction of Cp$\rm\sb2TiPh\sb2$ with dithiol. The spectroscopic and analytical data are consistent with the formulation of 2.1 and 2.2 as the bimetallic compounds Cp$\rm\sb2Ti(\mu$-S(CH$\sb2)\sb{\rm n}\rm S)\sb2TiCp\sb2$ (n = 2 2.1, n = 3 2.2). Source: Dissertation Abstracts International, Volume: 55-05, Section: B, page: 1842. Adviser: D. W. Stephan. Thesis (Ph.D.)--University of Windsor (Canada), 1993.
Recommended Citation
Nadasdi, Todd Timothy., "The characterization and chemistry of {\it mono\/}- and {\it bis\/}-cyclopentadienyl titanium thiolates." (1993). Electronic Theses and Dissertations. 3786.
https://scholar.uwindsor.ca/etd/3786