Date of Award

1993

Degree Type

Dissertation

Degree Name

Ph.D.

Department

Chemistry and Biochemistry

First Advisor

Stephan, D. W.,

Keywords

Chemistry, Inorganic.

Rights

CC BY-NC-ND 4.0

Abstract

The reactions of Cp$\rm\sb2TiCl\sb2$ with the dithiols, HS(CH$\sb2)\sb{\rm n}$SH (n = 2, 3) in the presence of imidazole proceed with formation of imidazole$\cdot$HCl affording relatively insoluble titanocene dithiolate derivatives 2.1 and 2.2 respectively. Alternatively, 2.2 can be prepared by the reaction of Cp$\rm\sb2TiPh\sb2$ with dithiol. The spectroscopic and analytical data are consistent with the formulation of 2.1 and 2.2 as the bimetallic compounds Cp$\rm\sb2Ti(\mu$-S(CH$\sb2)\sb{\rm n}\rm S)\sb2TiCp\sb2$ (n = 2 2.1, n = 3 2.2). Source: Dissertation Abstracts International, Volume: 55-05, Section: B, page: 1842. Adviser: D. W. Stephan. Thesis (Ph.D.)--University of Windsor (Canada), 1993.

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