Document Type
Article
Publication Date
10-2012
Publication Title
Synlett
Volume
23
Issue
16
First Page
2371
Keywords
allylation, electrophilic aromatic substitution, indium, metathesis, umpolung
Last Page
2371
Abstract
The products corresponding to the reactions of arenes and γ-carbonyl cations may be obtained by a one-pot, bicatalytic process involving InCl3-catalyzed arene allylation and cross metathesis with electron-deficient alkenes. The process is successful with electronically neutral and electron-rich arenes, and modestly Lewis basic donor groups are tolerated with an increase in InCl3 loading from 10 mol% to 15 mol%, and in one case, 20 mol%.
DOI
10.1055/s-0032-1317045
Funding Reference Number
NSERC
Recommended Citation
Henkie, Jake R.; Dhaliwal, Sugadar; and Green, James R.. (2012). Bicatalytic Allylation–Cross-Metathesis Reactions as γ-Carbonyl Cation Equivalents. Synlett, 23 (16), 2371-2371.
https://scholar.uwindsor.ca/chemistrybiochemistrypub/67
Comments
First published in Synlett, copyright © Georg Thieme Verlag, an imprint of Thieme Publishing. To access the final version, see DOI: 10.1055/s-0032-1317045 at https://www.thieme-connect.com/products/ejournals/html/10.1055/s-0032-1317045.