Document Type
Article
Publication Date
5-2017
Publication Title
Dalton Transactions
Volume
46
First Page
9769
Last Page
9776
Abstract
The synthesis of novel trithiobisphosphines is achieved by oxidative addition of tetrathiocins to the phosphorus(I) reagent [PIdppe][Br] in good yields under ambient conditions. These trithiobisphosphines and the related intermediate diphosphine species are characterized by X-ray diffraction and multinuclear NMR and a mechanism is proposed for the formation of these molecules.
DOI
10.1039/C7DT01345K
Recommended Citation
Kosnik, Stephanie C.; Nascimento, Maxemilian C.; Rawson, Jeremy M.; and Macdonald, Charles L.B.. (2017). Synthesis of bis(trithio)phosphines by oxidative transfer of phosphorus(I). Dalton Transactions, 46, 9769-9776.
https://scholar.uwindsor.ca/chemistrybiochemistrypub/91
COinS
Comments
This is an accepted manuscript. The version of record is available at https://doi.org/10.1039/C7DT01345K.