Synthesis of bis(trithio)phosphines by oxidative transfer of phosphorus(I)

Authors

Stephanie C. Kosnik
Maxemilian C. Nascimento
Jeremy M. Rawson, University of WindsorFollow
Charles L.B. Macdonald, University of WindsorFollow

Document Type

Article

Publication Date

5-2017

Publication Title

Dalton Transactions

Volume

46

First Page

9769

Last Page

9776

Abstract

The synthesis of novel trithiobisphosphines is achieved by oxidative addition of tetrathiocins to the phosphorus(I) reagent [P^Idppe][Br] in good yields under ambient conditions. These trithiobisphosphines and the related intermediate diphosphine species are characterized by X-ray diffraction and multinuclear NMR and a mechanism is proposed for the formation of these molecules.

DOI

10.1039/C7DT01345K

Comments

This is an accepted manuscript. The version of record is available at https://doi.org/10.1039/C7DT01345K.

Recommended Citation

Kosnik, Stephanie C.; Nascimento, Maxemilian C.; Rawson, Jeremy M.; and Macdonald, Charles L.B.. (2017). Synthesis of bis(trithio)phosphines by oxidative transfer of phosphorus(I). Dalton Transactions, 46, 9769-9776.
https://scholar.uwindsor.ca/chemistrybiochemistrypub/91