Generation and reactivity of the dehydrotropylium-Co(2)(CO)(6) ion

Authors

Sheida Amiralaei
James R. Green, University of WindsorFollow

Document Type

Article

Publication Date

2008

Publication Title

Chemical Communications

Issue

40

Abstract

Dehydrotropylium-Co(2)(CO)(6) ion (2) has been generated by the Lewis acid mediated ionization of alcohol (3); it is attacked by relatively strong nucleophiles (N > 1), but undergoes a radical homocoupling in the presence of weak nucleophiles (N < 1).

Comments

This article was first published in Chemical Communications and is available here. Copyright (2012) Royal Society of Chemistry.

Recommended Citation

Amiralaei, Sheida and Green, James R.. (2008). Generation and reactivity of the dehydrotropylium-Co(2)(CO)(6) ion. Chemical Communications (40).
https://scholar.uwindsor.ca/chemistrybiochemistrypub/1