Author ORCID Identifier
https://orcid.org/0000-0002-2659-288X : Brent St. Onge
https://orcid.org/0000-0003-2334-4503 : James Green
Document Type
Article
Publication Date
8-4-2021
Publication Title
Organic & Biomolecular Chemistry
Abstract
The γ-carbonyl cations generated from propargyl ether-Co2(CO)6 complexes undergo intramolecular Nicholas reactions to give dehydrobenzoxacin-3-one-Co2(CO)6 complexes in good yields. Reductive decomplexation and subsequent manipulation allows the synthesis of (±)-heliannuol K methyl ether and the formal syntheses of (±)-heliannuol K, (±)-heliannuol A, and (−)-heliannuol L.
DOI
10.1039/D1OB01395E
Funding Reference Number
NSERC, RGPIN-2016-04946
Recommended Citation
St. Onge, Brent and Green, James R.. (2021). The formation of benzoxacin-3-ones via intramolecular Nicholas reactions and synthesis of 8-membered heliannuols. Organic & Biomolecular Chemistry.
https://scholar.uwindsor.ca/chemistrybiochemistrypub/164