Document Type
Article
Publication Date
9-2017
Publication Title
Chemical Communications
Issue
82
First Page
11310
Last Page
11313
Abstract
Inclusion of the dithiadiazolyl radical PhCNSSN• into the dynamically porous metallocycle [Cu2(L1)2Cl4], where L1 is the bidentate ligand 1,3-bis(imidazol-1-ylmethyl)-2,4,6- trimethylbenzene, has been achieved by gas phase diffusion. Single crystal X-ray diffraction, powder X-ray diffraction, UV-visible spectroscopy, EPR and SQUID magnetometry studies confirm inclusion of the radical into this seemingly non-porous material, and illustrate the presence of antiferromagnetic coupling between the paramagnetic host and guest species. The radical guest is readily released by heating or by the addition of solvent (CH2Cl2).
DOI
10.1039/C7CC06678C
Recommended Citation
Nikolayenko,, Varvara I.; Barbour, Leonard J.; Arauzo, Ana; Campo, Javier; Rawson, Jeremy M.; and Haynes, Delia A.. (2017). Inclusion of a dithiadiazolyl radical in a seemingly non-porous solid. Chemical Communications (82), 11310-11313.
https://scholar.uwindsor.ca/chemistrybiochemistrypub/92
Comments
This is the accepted version of an article first published in Chemical Communications and available at https://doi.org/10.1039/C7CC06678C.